By Bernard S. Covino Jr.
ASM instruction manual, Vol. 13A: Corrosion: basics, defense and Prevention
The objective of ASM instruction manual, quantity 13A: Corrosion: basics, checking out, and safeguard is to assist engineers and architects comprehend corrosion with a view to remedy current corrosion difficulties and forestall destiny ones. it may be the 1st publication you decide whilst gaining knowledge of a corrosion challenge. The assurance of the amount has been thoroughly revised to make sure that it's the so much accomplished, useful, and updated source to be had. each one article is listed to different applicable sections of the guide, and every presents a highway map to the millions of person bibliographical references that have been used to assemble the knowledge.
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Extra resources for ASM Handbook: Corrosion : Fundamentals, Testing, and Protection
L. H. Freeman, 1964, p 338–360 E. Protopopoff and P. Marcus, Electrode Potentials, Corrosion: Fundamentals, Testing, and Protection, Vol 13A, ASM Handbook, ASM International, 2003, p 8–12 Electrode Potentials E. Protopopoff and P. Marcus, Ecole Nationale Supérieure de Chimie de Paris, Université Pierre et Marie Curie Cell Potentials and the Electromotive Force Series The standard equilibrium potentials measured at 25 °C (77 °F) relative to the SHE for various metal-ion electrodes can be tabulated in a series, called the emf series, shown in Table 1.
M. Pourbaix, Thermodynamics of Dilute Aqueous Solutions, Arnold Publications, 1949 3. W. N. Pourbaix—Palladium Award Medalist, J. Eletrochem. , Vol 123, 1976, p 23C 4. M. Pourbaix, Atlas of the Electrochemical Equilibria, NACE, 1974 E. Protopopoff and P. Marcus, Potential versus pH (Pourbaix) Diagrams, Corrosion: Fundamentals, Testing, and Protection, Vol 13A, ASM Handbook, ASM International, 2003, p 17–-30 Potential versus pH (Pourbaix) Diagrams E. Protopopoff and P. Marcus, CNRS, Ecole Nationale Supérieure de Chimie de Paris, Université Pierre et Marie Curie Calculation and Construction of E-pH Diagrams Potential-pH diagrams are based on thermodynamic calculations.
In this case, the liquid junction potential has been neglected. The IR drop constitutes a second unknown value in a single equation. It must be eliminated or minimized. The Luggin capillary is a tube, usually made of glass, that has been narrowed by elongation at one end. The narrow end is placed as close as possible to the test electrode surface (Fig. 1), and the other end of the tube goes to the reference electrode compartment. The Luggin capillary is filled with cell electrolyte, which provides an electric link between the reference and the test electrode.
ASM Handbook: Corrosion : Fundamentals, Testing, and Protection by Bernard S. Covino Jr.