Download PDF by Mohamed S. El-Aasser (auth.), Françoise Candau, Ronald H.: An Introduction to Polymer Colloids

By Mohamed S. El-Aasser (auth.), Françoise Candau, Ronald H. Ottewill (eds.)

ISBN-10: 0792306007

ISBN-13: 9780792306009

ISBN-10: 9400905211

ISBN-13: 9789400905214

The progress of curiosity within the topic of Polymer Colloids over the past twenty 5 years or so has been very huge ensuing now in significant overseas meetings on an annual foundation and lots of nationwide ones in addition. The curiosity stems not just from the wide variety of purposes of those fabrics but in addition from a interest as to the mechanism of formation and their starting to be use as version debris to enquire basic elements of physics and chemistry. In July 1988 a NATO complicated learn Institute was once held in Strasbourg, France, on the Centre St. Thomas. As an instructional advent to this I nstitute a sequence of 8 lectures used to be given to hide the elemental features of the topic. those 8 lectures have now been compiled into an Introductory textual content masking, emulsion poly­ merization, dispersion polymerization, inverse emulsion polymerization, the morphology of copolymer latices, the colloidal homes of latices, characterization equipment and rheology. it truly is was hoping that those will serve a large viewers, undergraduates, graduate-students and examine staff, either in and academe. The chapters all include evaluate fabric modern on the time of ebook. fhe 1988 NATO complicated examine I nstitute used to be made attainable via a furnish from the NATO-AS I programme and the subsequent businesses: BASF, Ludwigshafen, West Germany The Dow Chemical corporation, Michigan, united states Dow Chemical Rheinwerk GmbH, Rheinmunster, West Germany ICI PLC, Runcorn, England S. C. Johnson and Son Inc., Racine, united states NORSOLOR, Verneuil en Halatte, France Rhone Poulenc, Aubervilliers, France.

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Initially, all of the components are soluble in the dispersion medium to give a homogeneous solution. Upon initiation of the reaction the solution remains transparent for a finite period of time after which the reaction mixture becomes cloudy as the nuclei formed act as scattering centres. Provided these nuclei are well stabilized against coagulation the particles continue to grow as discrete entities until the reaction is terminated. A schematic diagram of the particle polymerization process is shown in Figure 1.

Figure 7 shows the size of the resulting particles plotted against the number of carbon atoms in the alcohol used as the dispersion medium. Figure 7 shows that the particle size increases upon passing from methanol to pentanol and then decreases again. ,jl-----'--~ o 20 MONOMER CONCENTRATION 40 / WT % Figure 6: Shows the final particle diameter plotted against the initial concentration of monomer in the dispersion polymerization of styrene in an ethanol/water medium attempt to explain his data.

77. 78. 79. 80. 81. 82. 83. 84. 85. 86. 87. 88. 89. 90. 91. 92. 93. 94. 95. 96. 97. 98. 99. 100. 101. 102. 103. W. , 1981, 32, 583. N.. 79. Orr, if:""""J. , 1960, 38, 668. Piirma, I. C. in Emulsion PolymeriZation, Eds. I. L. , 1976. Connor, P. , 1971, 37, 642. A. , 1978, 16, 677. S. , in Polymer Colloids II, Ed. M. Fitch, Plenum, New York, 1980. , 1969, 31, 19. Piirma, I. , 1980 . , 90. B. H. in Surfactants in Chemical/Process Engineering, Eds. D. T. E. O. , 1988,263-314. , Herbeck, R. , 1956, ~ 334.

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An Introduction to Polymer Colloids by Mohamed S. El-Aasser (auth.), Françoise Candau, Ronald H. Ottewill (eds.)

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