K. L. Mittal (Eds.)'s Adsorption at Interfaces PDF

By K. L. Mittal (Eds.)

ISBN-10: 0841201749

ISBN-13: 9780841201743

ISBN-10: 0841202494

ISBN-13: 9780841202498

content material: Thermodynamics of adsorption and interparticle forces / D.H. Everett and C.J. Radke --
Configurational habit of remoted chain molecules adsorbed from athermal suggestions / M. Lal, M.A. Turpin, K.A. Richardson, and D. Spencer --
Equilibrium movie strain on a flat, low-energy good / Robert J. strong --
Binding of solute and solvent on the interface and the gibbs floor extra / D.K. Chattoraj and S.P. Moulik --
Mechanism of sulfonate adsorption on the silver iodide-solution interface / okay. Osseo-Asare, D.W. Fuerstenau, and R.H. Ottewill --
Adsorption of dyes on water-swollen and non-swelling sturdy substrates / S.R. Sivaraja Iyer, A.S. Chanekar, and G. Srinivasan --
Adsorption of polystyrene on graphon from toluene / Victor okay. Dunn and Robert D. Vold --
Adsorption of ionic surfactants to porous glass : the exclusion of micelles and different solutes from adsorbed layers and the matter of adsorption maxima / Pasupati Mukerjee and Aroonsri Anavil --
DTA learn of water in porous glass / Chaur-Sun Ling and W. Drost-Hansen --
Monolayer reports. five, Styrene-acrylic acid motion pictures on aqueous substrates / Erwin Sheppard and Noubar Tcheurekdjian --
interplay of calcium ions with the combined monolayers of stearic acid and stearyl alcohol at pH 8.8 / D.O. Shah --
touch angles in Newton-Black cleaning soap movies drawn from ideas containing sodium dodecyl sulphate and electrolyte / J.A. De Feijter and A. Vrij --
Stratification in loose liquid movies / J.W. Keuskamp and J. Lyklema --
floor chemical homes of hugely fluorinated polymers / Marianne okay. Bernett and W.A. Zisman --
impact of floor oxygen complexes on floor habit of carbons / Balwant Rai Puri --
floor homes of nickel hydroxide ahead of and after dehydration to nickel oxide / M. subject, F.J. Micale, C.L. Cronan, H. Leidheiser, Jr., and A.C. Zettlemoyer --
The size of low interfacial pressure through the spinning drop strategy / J.L. Cayias, R.S. Schechter, and W.H. Wade --
Adhesion of ice frozen from dilute electrolyte options / H.H.G. Jellinek --
Mechanism of olfaction defined utilizing interfacial rigidity measurements / D.V. Rathnamma --
function of double interactions and spreading strain in particulate soil removing / Hermann Lange.

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And O l i v i e r , J . P . , "0n Physical Adsorp­ tion," Interscience Publishers, New York, 1964. 13. Hill, T . L . , 1960. 14. , Proc. Chem. , 1958, p. 57. 15. , "Theory of Rate Processes," McGraw-Hill, N . Y . , 1941. 16. C. , Cleveland, Ohio, 1970. 17. Fowler, R . H . , and Guggenheim, E . A . , " S t a t i s t i c a l Thermodynamics," Cambridge University Press, London, 1952. 18. Berghausen, P . E . , Kraus, G . , "Fundamental Studies of the Adhesion of Ice to S o l i d s , " WADC Technical Report 55-44, 1955.

E . the mole f r a c t i o n of surface s i t e s that are occupied. This entropy term i s c o n f i g u r a t i o n a l ; i t arises from the p o s s i b i l i t y of permuting the molecules among the occupied molal entropy of transfer, liqui sorbed f i l m , i s given by, X W AS = - Rln τ — + Rln ^r- + AS. - S (3) l-x W internal ql ' The l a s t two terms i n Equation 3 can probably be neglected. These correspond, r e s p e c t i v e l y , to the changes i n i n t e r n a l , molecular degrees of freedom, and to the configurational entropy of the l i q u i d , considered as a q u a s i - l a t t i c e with occupied and vacant s i t e s .

Such s t r u c t u r a l features are, by d e f i n i t i o n , absent from a molecularly smooth surface. These preliminary r e s u l t s led us to turn to a Langmuir model, as being f a r easier to treat than a BET model. It was a n t i c i p a t e d that a s t r i c t l y Langmuirian model might break down when some possible values of molecular parameters were assumed — for example, the model might p r e d i c t high enough coverage that l a t e r a l i n t e r a c t i o n s would be important.

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Adsorption at Interfaces by K. L. Mittal (Eds.)

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